邯邢地区中生代侵入岩中磷灰石的成因矿物学研究     

梁贤 《地质与勘探》2020,56(5):969-984

氧逸度为有效的氧分压，是实验岩石学中重要的研究课题，岩浆的氧逸度是继温度、压力、浓度等影响成岩成矿过程的关键性物理化学参数。本文利用磷灰石的氧逸度计，对邯邢地区六大主要岩体的岩浆氧逸度进行了计算。研究结果显示，样品中的磷灰石主要为羟-氟磷灰石，磷灰石的形态、成分和结构特征指示其为岩浆成因。磷灰石中的Mn元素在晶格中有两种方式，多以Mn3＋和Mn5＋的方式进入晶格。磷灰石氧逸度计计算的logfo2为-12.31~-9.75，均值-11.02。参考与磷灰石共生角闪石的形成温度，认为邯邢地区岩浆岩普遍具有较高的氧逸度。根据磷灰石氧逸度值与矿床规模的填图结果，认为并非氧逸度越高越有利于邯邢式铁矿的形成。结合矿物学填图等值线闭合的趋势，进而推断邯邢地区中部的符山和武安岩体深部可能仍存在较好的找矿远景。  相似文献   

不同盐度对文蛤(Meretrix meretrix)呼吸代谢及体内酶活性的影响     

白奕天  丁天扬  李东东  聂鸿涛  闫喜武 《海洋科学》2018,42(6):123-131

为研究不同盐度对文蛤呼吸代谢的影响,本实验设置5个盐度(‰)梯度(11、18、25、32、39),检测不同盐度对文蛤(Meretrixmeretrix)耗氧和排氨的影响,以及文蛤的外套膜、鳃、肝胰腺三种组织中乳酸脱氢酶和Na+/K+-ATP酶活性的变化。结果表明:随着盐度的不断升高,文蛤耗氧率先升后降再升,在盐度18时达到最大值;排氨率先升后降,在盐度32时达到最大值。随着盐度不断升高和胁迫时间延长,文蛤的肝胰腺中乳酸脱氢酶活力总体呈先升高后下降再升高的趋势(P0.05),酶活力在盐度39时为最高;随着盐度不断升高和胁迫时间延长,文蛤的外套膜中Na+/K+-ATP酶活力总体呈先下降再升高后下降的趋势(P0.05),在盐度32时为最高;文蛤的外套膜和鳃中乳酸脱氢酶活力以及鳃和肝胰腺中Na+/K+-ATP酶活力受盐度影响不显著(P0.05),酶活力变化也多呈现"W"形的变化趋势。研究结果为文蛤的人工养殖提供参考。  相似文献   

The role of fog,orography, and seasonality on precipitation in a semiarid,tropical island          下载免费PDF全文

Sarah R. Schmitt  Diego A. Riveros‐Iregui  Jia Hu 《水文研究》2018,32(18):2792-2805

Isotopes of water (²H/¹H and ¹⁸O/¹⁶O) are commonly used to trace hydrological processes such as moisture recycling, evaporation loss, and moisture source region and often vary temporally in a given region. This study provides a first‐ever characterization of temporally variable precipitation mechanisms of San Cristóbal Island, Galápagos. We collected fog, rain, and throughfall samples over three field seasons to understand the mechanisms driving seasonal‐ and event‐based variability in the isotopic composition of precipitation in Galápagos. We establish that fog is a common phenomenon in San Cristóbal, especially during the dry season, and we found that fog, compared with cocollected rainfall, is consistently enriched. We further suggest that the relative contribution of fog formed via different mechanisms (orographic, advective, radiation) varied seasonally. We found that the source region is the most dominant control of the isotopic composition of rainfall in the Galápagos at both the seasonal and event scales, but subcloud evaporative processes (the nontraditional manifestation of the amount effect) became a dominant control on the isotopic composition of rainfall during the dry season. Overall, our findings suggest that understanding seasonally variable water‐generating mechanisms is required for effective water resource management in San Cristóbal Island and other semiarid island ecosystems under current and future regimes of climate change.  相似文献   

哈达贺休盐湖卤水氢氧同位素特征及成因分析          下载免费PDF全文

马正明  山发寿  姜盼武  李庆宽  魏海成  李永寿 《盐湖研究》2020,28(1)

内蒙古哈达贺休盐湖蕴藏着较为丰富的地下卤水资源，但人们对其成因和演化机制尚缺乏充分的认识。本文采用稳定同位素方法，研究了哈达贺休盐湖地下卤水及其周边水体的氢氧同位素组成特征，并对卤水的成因进行了分析。结果表明：哈达贺休盐湖地下卤水的?D和?18O值平均值分别为-0.53 ‰和4.01 ‰，黑河河水的?D和?18O值平均值分别为-36.73 ‰和-5.51 ‰，居延海湖水的?D和?18O值平均值分别为1.26 ‰和2.73 ‰，当地大气降水的?D和?18O值平均值分别为-5.30 ‰和-1.20 ‰。研究区水体的蒸发趋势线方程为δD=5.32δ18O-20.08，该蒸发线偏离全球大气降水线。黑河河水的氘盈余值（d）最大，湖水和地下卤水的最小，而且湖水和卤水的d值与TDS呈负相关关系。偏正的?D和?18O值以及较小的d值，表明研究区卤水经历了强烈的蒸发，同时还存在与含氧类矿物的同位素交换反应。卤水和居延海湖水氢氧同位素值分布比较集中并且接近，二者都由黑河河水演化而来。  相似文献   

Cu–Mo Differential Mineralization Mechanism of the Dabate Polymetallic Deposit in Western Tianshan,NW China: Evidence from Geology,Fluid Inclusions,and Oxygen Isotope Systematics     

Rui Cao  Shengchao Yan  Bin Chen  Keke Sun  Qinglin Zhang  Haodong Gu 《Resource Geology》2020,70(1):50-69

Classic porphyry Cu–Mo deposits are mostly characterized by close temporal and spatial relationships between Cu and Mo mineralization. The northern Dabate Cu–Mo deposit is a newly discovered porphyry Cu–Mo polymetallic deposit in western Tianshan, northwest China. The Cu mineralization postdates the Mo mineralization and is located in shallower levels in the deposit, which is different from most classic porphyry Cu–Mo deposits. Detailed field investigations, together with microthermometry, laser Raman spectroscopy, and O‐isotope studies of fluid inclusions, were conducted to investigate the origin and evolution of ore‐forming fluids from the main Mo to main Cu stage of mineralization in the deposit. The results show that the ore‐forming fluids of the main Mo stage belonged to an NaCl + H₂O system of medium to high temperatures (280–310°C) and low salinities (2–4 wt% NaCl equivalent (eq.)), whereas that of the main Cu stage belonged to an F‐rich NaCl + CO₂ + H₂O system of medium to high temperatures (230–260°C) and medium to low salinities (4–10 wt% NaCl eq.). The δ¹⁸O values of the ore‐forming fluids decrease from 3.7–7.8‰ in the main Mo stage to ?7.5 to ?2.9‰ in the main Cu stage. These data indicate that the separation of Cu and Mo was closely related to a large‐scale vapor–brine separation of the early ore‐forming fluids, which produced the Mo‐bearing and Cu‐bearing fluids. Subsequently, the relatively reducing (CH₄‐rich) Mo‐bearing, ore‐forming fluids, dominantly of magmatic origin, caused mineralization in the rhyolite porphyry due to fluid boiling, whereas the relatively oxidizing (CO₂‐rich) Cu‐bearing, ore‐forming fluids mixed with meteoric water and precipitated chalcopyrite within the crushed zone at the contact between rhyolite porphyry and wall rock. We suggest that the separation of Cu and Mo in the deposit may be attributed to differences in the chemical properties of Cu and Mo, large‐scale vapor–brine separation of early ore‐forming fluids, and changes in oxygen fugacity.  相似文献   

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet     

Alice Vho  Daniela Rubatto  Benita Putlitz  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):459-471

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.  相似文献   

温石棉通过活性氧激活线粒体通路诱导A549细胞凋亡的机制研究     

王玉琳  霍婷婷  董发勤  刘琬薰  杨洁  曾娅莉  邓建军 《岩石矿物学杂志》2018,37(2):318-324

探讨活性氧(reactive oxygen species,ROS)在温石棉激活线粒体通路诱导A549凋亡中的作用。采用不同浓度温石棉粉尘染毒人肺上皮细胞(A549)后,MTT法检测细胞存活率,流式细胞术检测ROS抑制剂N-乙酰半胱氨酸(N-acetyl-L-cysteine,NAC)预处理前后的细胞凋亡率、胞内ROS水平及线粒体膜电位,Western Blot法检测各组细胞半胱天冬氨酸蛋白酶3(caspase-3)、p53蛋白表达水平。实验结果显示,温石棉可降低A549细胞存活率,呈现时间-剂量效应关系;NAC可显著减少胞内ROS水平、阻止线粒体膜电位下降,并下调caspase-3、p53蛋白的表达水平,抑制部分细胞凋亡的发生。表明ROS可通过诱导p53蛋白过表达,激活线粒体凋亡通路,诱导A549细胞发生凋亡。  相似文献   

高压超高压变泥质岩适用的地质温压计评述     

王晓赛  杜瑾雪  田野 《岩石矿物学杂志》2018,37(2):325-341

高压超高压变泥质岩形成温压条件及p-T演化轨迹是高压超高压变质作用研究的重要内容。本文介绍了高压超高压变泥质岩适用的几种地质温压计,包括石榴子石-多硅白云母Fe~(2+)-Mg交换温度计、石榴子石-绿泥石Fe~(2+)-Mg交换温度计、硬绿泥石-绿泥石Fe~(2+)-Mg交换温度计、多硅白云母Si含量压力计、金红石Zr含量温度计、榍石Zr含量温压计、锆石Ti含量温度计、石英Ti含量温度计以及氧同位素温度计,并对上述温压计的适用条件及使用时的注意事项做了简要评述。  相似文献   

斑岩型钼矿床研究进展与问题   总被引：1，自引：0，他引：1  

曹冲  申萍 《地质论评》2018,64(2):477-497

本文在简要介绍全球重要成矿带斑岩型钼矿床品位、储量、时空分布以及构造背景的基础上,着重归纳了斑岩型钼矿床中Mo在岩浆—热液演化过程中的地球化学行为特征以及Mo在成矿流体中的迁移与沉淀机制两个方面的研究进展。取得了以下认识:形成斑岩型钼矿床成矿岩浆氧逸度(f_(O2))变化范围较大,但一般大于铁橄榄石—磁铁矿—石英(FMQ)缓冲体系。斑岩钼矿床形成的主要受岩浆房的大小,大体积的岩浆流体能否高效聚集到浅部岩株或岩脉,岩浆中的挥发分(例如F)含量等因素的控制,但与成矿花岗岩和出溶流体中Mo的含量高低无直接关系。成矿流体的氧逸度与p H降低对辉钼矿沉淀具有关键作用。除此之外,温度与盐度降低对辉钼矿沉淀也有重要作用。流体的多阶段沸腾可能对提高Mo品位具有重要意义。此外,应加强岩浆结晶分异过程、岩浆热液转化过程Mo的地球化学行为研究。  相似文献   

广西桂林凉风洞秋冬季滴水和沉积物氧同位素对极端降水的记录研究     

吴夏  潘谋成  曹建华  朱晓燕  张美良 《地球学报》2018,39(1):53-61

近年来,全球环境变化导致的极端气候事件的发生频率剧增,引起了国内外学者的广泛关注。由于器测记录时间较短,因此需要通过精确连续记录古气候变化的石笋来解译极端气候事件的规律。本文针对桂林凉风洞2015年9月至2016年1月的大气降水、洞穴滴水和现代沉积物的氧同位素组成进行了高分辨率的监测。监测结果揭示了由于秋冬水汽源的改变,导致桂林地区大气降水δD、δ~(18)O同位素值显示逐渐偏正的季节性变化,并且建立了该区域大气降水线为:δD=8.8δ~(18)O+16.38。由于大气降水作为凉风洞水源补给唯一来源,使得洞穴滴水的δ~(18)O继承大气降水的δ~(18)O所蕴含的环境信息,进而记录在洞穴现代沉积物中。但是受到洞穴顶部岩溶表层带的平滑或者均一化的作用,使得洞穴滴水的δ~(18)O同位素值要偏正于大气降水的δ~(18)O同位素值。在极端降水信号输入岩溶表层带后由于存在不同的水文地球化学过程,从而导致洞穴沉积物对其极端降水事件的响应时间存在不同,并且在δ~(18)O同位素值也存在明显差异。因此,系统监测洞穴滴水、沉积物δ~(18)O同位素对外界环境信息的响应过程,能为量化或精确解译石笋δ~(18)O同位素记录所指代的古气候环境信息提供基础。  相似文献